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BGC0002582NRPS

Guanipiperazine A;Guanipiperazine B

Producing organism
Streptomyces chrestomyceticus
Taxonomy
Bacteria›Actinomycetota›Actinomycetes›Kitasatosporales›Streptomycetaceae›Streptomyces
Biosynthetic class
NRPS (Type I)
Total steps
8
DOI
MIBiG entry
View on MIBiG ↗
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Gene Cluster Map5 genes · 7,207 bp

APCPTD1 kb7.2 kb visible · 7,207 bp total
Biosynthetic (core)
Biosynthetic (additional)
Unknown
Domains
AAdenylation (A)
PCPPeptidyl carrier (PCP)
TDTerminal reductase

Pathway Graphsteps arranged in biosynthetic order

8 steps · 7 edges
Step 1
QUF98525.1
+Tyrosine
Step 2MR
QUF98525.1
Step 3
QUF98525.1
+Tyrosine
Step 4MR
QUF98525.1
Step 5
QUF98524.1
Step 6
QUF98526.1
Step 7
QUF98527.1
+Guanine
Step 8
QUF98527.1
+Guanine
Starting stepIntermediateFinal product│ModuleLoadingTENo module│PKS stepNRPS stepTailoring/otherScroll to pan · Wheel to zoom

Biosynthetic Reactions8 steps

StepProduct IDEnzymeModuleSubstrateProduct SMILESNotes
12582-1QUF98525.1—
Tyrosine
OC(C(N)CC1=CC=C(O)C=C1)=O—
22582-2QUF98525.1MR
2582-1
from: 2582-1
O=CC(N)CC1=CC=C(O)C=C1—
32582-3QUF98525.1—
2582-2;Tyrosine
from: 2582-2
NC(CC1=CC=C(O)C=C1)/C=N/C(CC2=CC=C(O)C=C2)C(O)=O—
42582-4QUF98525.1MR
2582-3
from: 2582-3
OC(C=C1)=CC=C1CC2N=CC(CC3=CC=C(O)C=C3)N=C2—
52582-5QUF98524.1—
2582-4
from: 2582-4
OC(C=C1)=CC=C1CC2NCC(CC3=CC=C(O)C=C3)NC2—
62582-6QUF98526.1—
2582-5
from: 2582-5
OC1=CC=C2C=C1OC(C=C3)=CC=C3C[C@H]4CN[C@H](CN4)C2—
72582(1)QUF98527.1—
2582-6;Guanine
from: 2582-6
OC1=C(C2=NC3=C(N=C(N)NC3=O)N2)C=C4C=C1OC(C=C5)=CC=C5C[C@H]6CN[C@H](CN6)C4—
82582(2)QUF98527.1—
2582-6;Guanine
from: 2582-6
O=C1NC(N)=NC2=C1N=C(OC3=CC=C4C=C3OC(C=C5)=CC=C5C[C@H]6CN[C@H](CN6)C4)N2—
Click any row to view the chemical structure · Click a module badge (M1, TE…) to view domain architecture