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BGC0002466NRPS

Peucechelin

Producing organism
Streptomyces peucetius subsp. caesius ATCC 27952
Taxonomy
Bacteria›Actinomycetota›Actinomycetes›Kitasatosporales›Streptomycetaceae›Streptomyces
Biosynthetic class
NRPS (Type I)
Total steps
7
DOI
MIBiG entry
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peucechelin

Gene Cluster Map20 genes · 37,554 bp

CACAECACAC10 kb37.6 kb visible · 37,554 bp total
Biosynthetic (core)
Biosynthetic (additional)
Transport
Unknown
Domains
CCondensation (C)
AAdenylation (A)
PCPPeptidyl carrier (PCP)
EEpimerization (E)
TgrTIGR01720

Pathway Graphsteps arranged in biosynthetic order

7 steps · 8 edges
Step 1
Start
+L-Ornithine
Step 2
CGZ69_03805
Step 3
CGZ69_03810
Step 4M1
CGZ69_03795
+Acetyl-CoA
Step 5M2
CGZ69_03795
+Arginine
Step 6M3
CGZ69_03795
Step 7M4
CGZ69_03795, ?
Starting stepIntermediateFinal product│ModuleLoadingTENo module│PKS stepNRPS stepTailoring/otherScroll to pan · Wheel to zoom

Biosynthetic Reactions7 steps

StepProduct IDEnzymeModuleSubstrateProduct SMILESNotes
12466-1Start—
L-Ornithine
O=C(O)[C@@H](N)CCCN—
22466-2CGZ69_03805—
2466-1
from: 2466-1
O=C(O)[C@@H](N)CCCNO—
32466-3CGZ69_03810—
2466-2
from: 2466-2
O=C(O)[C@@H](N)CCCN(C(C)=O)O—
42466-4CGZ69_03795M1
Acetyl-CoA;2466-3
from: 2466-3
OC([C@H](CCCN(O)C([H])=O)NC(C)=O)=O—
52466-5CGZ69_03795M2
2466-4;Arginine
from: 2466-4
OC([C@@H](CCCNC(N)=N)NC([C@H](CCCN(O)C([H])=O)NC(C)=O)=O)=O—
62466-6CGZ69_03795M3
2466-5;2466-2
from: 2466-5, 2466-2
N[C@@H](CCCN(O)C([C@@H](CCCNC(N)=N)NC([C@H](CCCN(O)C([H])=O)NC(C)=O)=O)=O)C(O)=O—
72466CGZ69_03795, ?M4
2466-6;2466-3
from: 2466-6, 2466-3
O=C1[C@H](CCCN(O)C([C@@H](CCCNC(N)=N)NC([C@H](CCCN(O)C([H])=O)NC(C)=O)=O)=O)NC([C@H](CCCN(O)C([H])=O)N1)=O—
Click any row to view the chemical structure · Click a module badge (M1, TE…) to view domain architecture