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BGC0001742PKS

Piericidin A1

Producing organism
Candidatus Streptomyces philanthi bv. triangulum
Taxonomy
Bacteria›Actinomycetota›Actinomycetes›Kitasatosporales›Streptomycetaceae›Streptomyces
Biosynthetic class
PKS (Unknown)
Total steps
15
DOI
MIBiG entry
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Loading…
piericidin A1
C25H37NO4415.27 Da

Pathway Graphsteps arranged in biosynthetic order

15 steps · 14 edges
Step 1Load
CSP_7468
+Acetyl-CoA
Step 2M1
CSP_7468
+Methylmalonyl-CoA
Step 3M2
CSP_7467
+Methylmalonyl-CoA
Step 4M3
CSP_7467
+Methylmalonyl-CoA
Step 5M4
CSP_7466
+Malonyl-CoA
{'Missing':['AT']}
Step 6M5
CSP_7464
+Methylmalonyl-CoA
Step 7M6
CSP_7463
+Malonyl-CoA
Step 8M7
CSP_7462
+Methylmalonyl-CoA
Step 9M8
CSP_7462
+Malonyl-CoA
Step 10TE
CSP_7462
Step 11
CSP_7459
Step 12
CSP_7460
Step 13
CSP_7461
Step 14
CSP_7458
Step 15
CSP_7457
Starting stepIntermediateFinal product│ModuleLoadingTENo module│PKS stepNRPS stepTailoring/otherScroll to pan · Wheel to zoom

Biosynthetic Reactions15 steps

StepProduct IDEnzymeModuleSubstrateProduct SMILESNotes
11742-1CSP_7468Loading
Acetyl-CoA
O=C(O)C—
21742-2CSP_7468M1
1742-1;Methylmalonyl-CoA
from: 1742-1
C/C=C(C)/C(O)=O—
31742-3CSP_7467M2
1742-2;Methylmalonyl-CoA
from: 1742-2
C/C=C(C)/C(O)C(C)C(O)=O—
41742-4CSP_7467M3
1742-3;Methylmalonyl-CoA
from: 1742-3
C/C=C(C)/C(O)C(C)/C=C(C)/C(O)=O—
51742-5CSP_7466M4
1742-4;Malonyl-CoA
from: 1742-4
C/C=C(C)/C(O)C(C)/C=C(C)/C=C/C(O)=O{'Missing':['AT']}
61742-6CSP_7464M5
1742-5;Methylmalonyl-CoA
from: 1742-5
C/C=C(C)/C(O)C(C)/C=C(C)/C=C/CC(C)C(O)=O—
71742-7CSP_7463M6
1742-6;Malonyl-CoA
from: 1742-6
C/C=C(C)/C(O)C(C)/C=C(C)/C=C/CC(C)/C=C/C(O)=O—
81742-8CSP_7462M7
1742-7;Methylmalonyl-CoA
from: 1742-7
C/C=C(C)/C(O)C(C)/C=C(C)/C=C/CC(C)/C=C/C(C(C)C(O)=O)=O—
91742-9CSP_7462M8
1742-8;Malonyl-CoA
from: 1742-8
C/C=C(C)/C(O)C(C)/C=C(C)/C=C/CC(C)/C=C/C(C(C)C(CC(O)=O)=O)=O—
101742-10CSP_7462TE
1742-9
from: 1742-9
C/C=C(C)/[C@H](O)[C@H](C)/C=C(C)/C=C/CC(C)/C=C/C(C(C)C(CC(O)=O)=O)=O—
111742-11CSP_7459—
1742-10
from: 1742-10
C/C=C(C)/[C@H](O)[C@H](C)/C=C(C)/C=C/CC(C)/C=C/C(C(C)C(CC(N)=O)=O)=O—
121742-12CSP_7460—
1742-11
from: 1742-11
OC1=C(C)C(C/C=C(C)/C/C=C/C(C)=C/[C@@H](C)[C@@H](O)/C(C)=C/C)=NC(O)=C1—
131742-13CSP_7461—
1742-12
from: 1742-12
OC1=C(C)C(C/C=C(C)/C/C=C/C(C)=C/[C@@H](C)[C@@H](O)/C(C)=C/C)=NC(OC)=C1—
141742-14CSP_7458—
1742-13
from: 1742-13
OC1=C(C)C(C/C=C(C)/C/C=C/C(C)=C/[C@@H](C)[C@@H](O)/C(C)=C/C)=NC(OC)=C1O—
151742CSP_7457—
1742-14
from: 1742-14
OC1=C(C)C(C/C=C(C)/C/C=C/C(C)=C/[C@@H](C)[C@@H](O)/C(C)=C/C)=NC(OC)=C1OC—
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